הצגת המוצר

5,5-DIMETHYL-1,3-CYCLOHEXANEDIONE;5,5'-DIMETHYLCYCLOHEXANE-1,3-DIONE;5,5-DIMETHYL-CYCLOHEXANE-1,3-DIONE;5,5-DIMETHYLDIHYDRORESORCINOL;1,1-Dimethyl-3,5-cyclohexanedione;1,1-Dimethyl-3,5-diketocyclohexane;1,3-Cyclohexanedione, 5,5-dimethyl-;1,3-Cyclohexanedione,5,5-dimethyl-
126-81-8
C8H12O2
140.18
204-804-4
Pyridines ,Halogenated Heterocycles;Building Blocks;C7 to C8;Carbonyl Compounds;Chemical Synthesis;Ketones;Pharmaceutical Intermediates;Aromatic Ketones (substituted);ketone;Materials Science;Organic Building Blocks;bc0001
126-81-8.mol
Dimedone Structure
 
146-148 degree (lit.)
216.69 degree (rough estimate)
1.0373 (rough estimate)
1.4787 (estimate)
4.01g/l
4.8(at 25 degree )
0.416 g/100 mL (25 ºC)
14,3242
471489
BADXJIPKFRBFOT-UHFFFAOYSA-N
1.3 at 20 degree
126-81-8(CAS DataBase Reference)
Dimedone(126-81-8)
1,3-Cyclohexanedione, 5,5-dimethyl- (126-81-8)
 
36/37/38
24/25-36-26
2
GV0345000
F 8-9
29142900
 
5,5-Dimethyl-1,3-cyclohexanedione
 
Part of furannulation strategy for the synthesis of naturally occurring fused 3-methylfurans.1
Used in the synthesis of fused 3-methylfurans via furannulation.
Reagent used in synthesis of fused 3-methylfuransDimedone is used in organic chemistry to identify the presence of aldehyde group. It is also used as a catalyst in the formation of transition-metal complexes. Further, it is also employed in colorimetry, crystallography, luminescence and spectrophotometric analysis. In addition to this, it is used in the synthesis of naturally occurring fused 3-methylfurans.
Journal of the American Chemical Society, 77, p. 6656, 1955 10.1021/ja01629a086
Organic Syntheses, Coll. Vol. 2, p. 200, 1943
5,5-dimethyl-1,3-cyclohexanedione (Dimedone) is basically a highly sensitive and very specific reagent used for the determination of aldehydes. It is highly advantageous as it is environment friendly, give high yields and is a simple workup procedure.
Crystallise dimedone from acetone (ca 8mL/g), water or aqueous EtOH. Dry it in air. [Schneider & Todd Org Synth Coll Vol II 200 1943, Beilstein 7 H 559, 7 IV 1999.]
 
3,3-Dimethylglutaric acid-->3-CHLORO-5,5-DIMETHYL-2-CYCLOHEXEN-1-ONE-->5-METHOXY-3-OXOVALERIC ACID METHYL ESTER-->DDE-OH-->2-ACETYLDIMEDONE

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